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President Matt Santos, The West Wing (Jimmy Smits) Yes, we already had a president from The West Wing on the list, but it would be a crime to leave off President Matt Santos. President Bartlet’s successor was about to return to Texas and leave the world of Washington behind when deputy White House chief of staff Josh Lyman (Bradley Whitford) convinced him to run for office (thank you, Josh. Thank you.) We didn’t get to see much of President Santos in office, following his election on the tragic night of his running mate’s death, but we’re sure he did some great things.